第53卷第2期2024年2月糠醛MPV还原制糠醇中固体酸碱催化剂的研究进展杨荣何,李伏坤,杜子婷，代金杭，曹卿雅,杨德龙（重庆工商大学环境与资源学院催化与环境新材料重庆市重点实验室，重庆400067）摘要：介绍了固体酸碱催化剂在糠醛Meerwein-Ponndorf-Verley（MPV）还原制糠醇中的研究进展。糠醛作为高度商品化的生物基平台化合物,其可通过加氢还原为更具有经济价值的化学品。MPV还原因其条件温和、安全和环保而受到生物炼制领域青崃。介绍MPV典型反应及六元环过渡态的形成过程；对不同固体酸碱催化剂在糠醛MPV还原制糠醇中的研究进展进行总结,其中锆/铪基催化剂具有优异的MPV还原性能被广泛研究；针对固体酸碱催化剂在该领域进行总结，并指出存在的主要问题和解决方法，同时对该领域未来的发展进行展望。关键词：固体酸碱催化剂；糠醛；糠醇；MPV还原中图分类号：TQ032.4;TQ031.4文献标识码：AAdvancesinsolidacid-basecatalystsintheproductionoffurfuralalcoholfromfurfuralthroughMPVreductionYANGRong-he,LIFu-kun,DUZi-ting,DAIJin-hang,CAOQing-ya,YANGDe-long(ChongqingKeyLaboratoryofCatalysisandNewEnvironmentalMaterials,CollegeofEnvironmentandResources,ChongqingTechnologyandBusinessUniversity,Chongqing400067,China)Abstract:Theresearchprogressofsolidacid-basecatalystsinthereductionoffurfuralMeerwein-Ponndorf-Verley(MPV)tofurfurylalcoholwasreviewed.Asahighlycommercializedbiologicalplatformcompound,furfuralcanbereducedintomoreeconomicalchemicalsbyhydrogenation.MPVreductionisfavoredinthefieldofbio-refiningbecauseofitsmildconditions,safetyandenvironmentalprotection.ThetypicalreactionsofMPVandtheformationofsix-memberedringtransitionstatesareintroduced,andtheresearchprogressofdifferentsolidacid-basecatalystsinthereductionoffurfuraltofurfurylalcoholwithMPVissummarized,theexcellentMPVreductionperformanceofzirconium/hafnium-basedcatalystshasbeenwidelystudied.Asummaryofsolidacid-basecatalystsinthisfieldandthemainproblemsandsolu-tionsinthisfieldarepointedout,atthesametime,thefuturedevelopmentofthisfieldisprospected.Keywords:solidacid-basecatalysts;furfural;furfurylalcohol;MPVreduction自工业化以来，人类大量燃烧化石燃料导致温室气体排放，加速全球变暖，...
