第53卷第2期2024年2月（1.广东工业大学轻工化工学院，广东广州510006；2.南方海洋科学与工程广东省实验室（湛江），广东湛江：524000）摘要：首先阐述了目前限制着卤化金属配位聚合物（XCP）材料发展的关键问题，如热稳定性、耐湿性较差、重金属渗出等。随后提到将卤素配位原子引人传统配位聚合物中，这种策略既有效提高材料的光吸收能力，又能稳定激发态电子,对增强材料的光催化性能具有重要意义。进一步综述了卤化金属配位聚合物材料在光催化降解有机污染物、选择性有机合成、水裂解产氢以及CO，还原方面的研究，并对该类材料在光催化领域的应用进行展望，为构建长效稳定的XCP实现高效光催化,扩大应用规模以及探究结构和性能之间的构效关系提供理论参考。关键词：配位聚合物；卤化金属；光催化；应用中图分类号：TQ050.4*21;0641Applicationofmetalhalidecoordinationpolymerinphotocatalysis(1.SchoolofChemicalEngineeringandLightIndustry,GuangdongUniversityofTechnology,Guangzhou510006,China;2.SouthernMarineScienceandEngineeringGuangdongLaboratory(Zhanjiang),Zhanjiang524000,China)Abstract:Thispaperfirstdescribesthekeyproblemsthatlimitthedevelopmentofmetal-halidecoordina-tionpolymer(XCP)materials,suchaspoorthermalstability,moistureresistance,heavymetalexudationandsoon.Thenitismentionedthatthehalogencoordinationatomisintroducedintothetraditionalcoor-dinationpolymer.Thisstrategycannotonlyeffectivelyimprovethelightabsorptioncapacityofthemateri-al,butalsostabilizetheexcitedelectrons,whichisofgreatsignificancetoenhancethephotocatalyticper-formanceofthematerial.Thispaperfurtherreviewstheresearchonthephotocatalyticdegradationofor-ganicpollutants,selectiveorganicsynthesis,hydrogenproductionfromwatercrackingandCO,reductionofhalogenatedmetalcoordinationpolymermaterials,andprospectstheapplicationofsuchmaterialsinthefieldofphotocatalysis.Inordertoconstructlong-termstableXCPtoachieveefficientphotocatalysis,toprovidetheoreticalreferenceforexpandingtheapplicationscaleandexploringthestructure-activityrela-tionshipbetweenstructureandperformance.Keywords:coordinationpolymer;metalhalide;photocatalysis;application配位聚合物（coordinationpolymer）是...
