9.Mass-actionkinetics(质量作用动力学)ReactingstreamsofcombustinggasesareamongtheReactingstreamsofcombustinggasesareamongthemostimportantanddifficultflowproblemsstudied.mostimportantanddifficultflowproblemsstudied.1)thespeciescontinuityequation:1)thespeciescontinuityequation:providesourceandsinktermsforprovidesourceandsinktermsforhomogeneousreactionshomogeneousreactions2)theenergyequation:importantheat2)theenergyequation:importantheatsourceorsinktermforthecreationandsourceorsinktermforthecreationanddestructionofspecies.destructionofspecies.Chapter9:setsoutthebasicformulationandChapter9:setsoutthebasicformulationandgoverningequationsofmass-actionkinetics.governingequationsofmass-actionkinetics.theseequationsdescribethetimeevolutionofchemicaltheseequationsdescribethetimeevolutionofchemicalspeciesduetochemicalreactionsinthegasphase.speciesduetochemicalreactionsinthegasphase.Chapter10:theoriesofgas-phasechemicalreactionChapter10:theoriesofgas-phasechemicalreactionrate.Chapter11:heterogeneouschemicalreactionsatarate.Chapter11:heterogeneouschemicalreactionsatagas-solidinterface.gas-solidinterface.Section9.1:TheGibbsfreeenergySection9.1:TheGibbsfreeenergyDeterminingthedrivingDeterminingthedrivingforce(spontaneityforce(spontaneity自发性自发性)ofchemical)ofchemicalreactions,thepositionofchemicalreactions,thepositionofchemicalequilibrium,andtheequilibriumconstant.equilibrium,andtheequilibriumconstant.Section9.2:therelatedthermodynamicquantity,andSection9.2:therelatedthermodynamicquantity,andtheequilibriumconstant.theequilibriumconstant.Section9.3:Gas-phasemass-actionkineticsSection9.3:Gas-phasemass-actionkineticsGeneralexpressionsforspeciesproduction/Generalexpressionsforspeciesproduction/destructionratesofhomogeneouschemicalreactionsdestructionratesofhomogeneouschemicalreactionsSection9.4and9.5:PressureeffectsforunimolecularSection9.4and9.5:Pressureeffectsforunimolecular((单分子单分子)andbimolecular()andbimolecular(双分子双分子)reactionrates.)reactionrates.9.1Gibbsfreeener...
