吉林大学《858有机化学》模拟题二解析模拟套卷精讲模拟四套卷精讲一、反应题（50分，每个产物2分）1【解题思路】NBS溴代试剂，炔烃的还原，以及卡宾反应。CH3NBSROOR⑴CNaC⑵NaNH3⑶CH2IZn⑷模拟四套卷精讲【答案要点】CH3NBSROOR⑴CNaC⑵NaNH3⑶CH2IZn⑷模拟四套卷精讲2、【解题思路】烯烃的过氧氧化，格式试剂的反应，氯代反应。CH2CCH3CH3CH3COOOH(5)CH2MgBrH3+O(6)SOCl2(7)模拟四套卷精讲【答案要点】CH2CCH3CH3CH3COOOH(5)CH2MgBrH3+O(6)SOCl2(7)模拟四套卷精讲3、(9)【解题思路】烯烃的氧化，以及开环还原。OsO4(8)H+模拟四套卷精讲【答案要点】(9)OsO4(8)H+模拟四套卷精讲4【解题思路】醚的开环以及还原。N(CH3)OHPhO(10)Hg(OAc)2NaBH4(11)HI1mol(12)模拟四套卷精讲【答案要点】N(CH3)OHPhO(10)Hg(OAc)2NaBH4(11)HI1mol(12)模拟四套卷精讲5【解题思路】酮的氨解，酸性条件下水解。ONH2OH(13)H3+O(14)CH3NH2(15)模拟四套卷精讲【答案要点】ONH2OH(13)H3+O(14)CH3NH2(15)模拟四套卷精讲6【解题思路】酮的还原以负碳离子反应。H3+O2CH3COCH3Ba(OH)2(16)CH2(COOC2H5)2NaOC2H5(17)H3+OOH-(18)模拟四套卷精讲【答案要点】H3+O2CH3COCH3Ba(OH)2(16)CH2(COOC2H5)2NaOC2H5(17)H3+OOH-(18)模拟四套卷精讲7【解题思路】负碳离子反应。H3+OOH-OO浓(19)模拟四套卷精讲【答案要点】H3+OOH-OO浓(19)模拟四套卷精讲8【解题思路】负碳离子反应。OONaOH(20)(21)SOHH2C(CH3)2模拟四套卷精讲【答案要点】OONaOH(20)(21)SOHH2C(CH3)2模拟四套卷精讲9【解题思路】负碳离子反应。CH2COOC2H5ONaOC2H5I2OH-H3+O(22)P2O5(23)模拟四套卷精讲【答案要点】CH2COOC2H5ONaOC2H5I2OH-H3+O(22)P2O5(23)模拟四套卷精讲10、【解题思路】负碳离子反应。CH2CH2OOC2H5NaOC2H5OCl(24)NaCH3OH(25)模拟四套卷精讲CH2CH2OOC2H5NaOC2H5OCl(24)NaCH3OH(25)【答案要点】模拟四套卷精讲二、机理题（30分，每题10分）1、CHO﹢CNCN-OCN模拟四套卷精讲【答案要点】CHO﹢CNCN-OCN模拟四套卷精讲2、写出异丙苯氧化水解法合成苯酚的机理CH3CHCH3CH3CHCH3ClAlCl31.O22.H3+OCH3CCH3OHO+模拟四套卷精讲【答案要点】CH3CH3CHO2CH3CH3COHO过氧化异丙苯H+CH3CH3COH2O-H2OCH3CH3COCH3CH3COH2OCH3CH3COH2O-H+CH3CH3COHOCH3CH3COHO+CH3CCH3O+OH模拟四套卷精讲3、写出下列反应机理OCH3CCH2COOC2H5OCH3CH=CCCH3O+NaOC2H5CH3CH3COOC2H5COOC2H5COOC2H5【答案要点】CH3CCH2COOC2H5ONaOC2H5CH3CCHCOOC2H5OCH3CH=C...
