Chem.J.ChineseUniversities,2023,44(7),2023006920230069(1/8)CHEMICALJOURNALOFCHINESEUNIVERSITIES高等学校化学学报研究论文交联PEDOT∶F空穴传输层提升柔性有机光伏电池性能的研究韦晚霞#，周先敏#，董馨韵，刘铁峰，谢聪，程靖宇，陈建平，陆鑫，冯凯，周印华（华中科技大学武汉光电国家研究中心,武汉430074）摘要银纳米线(AgNWs)顶电极是全溶液加工型有机太阳能电池(OSCs)的重要组成部分.然而,在涂布AgNWs乙醇溶液时,对下层空穴传输层有一定洗脱损坏.本文提出对空穴传输层聚(3,4-乙烯二氧噻吩)∶全氟磺酸离子聚合物(PEDOT∶F)进行交联,以提升其抗溶剂渗透能力.通过引入交联剂聚乙二醇二缩水甘油醚(PEGDE)实现了PEDOT∶F的交联,相应小面积柔性器件的效率为14.86%.进一步制备了21.18cm2的柔性有机光伏模组,其效率达到12.38%.关键词空穴传输层；PEDOT∶F；交联；银纳米线；柔性有机太阳能电池中图分类号TM914文献标志码Adoi：10.7503/cjcu20230069Cross-linkingPEDOT∶FHole-transportingLayertoEnhancePhotovoltaicPerformanceofFlexibleOrganicSolarCellsWEIWanxia#，ZHOUXianmin#，DONGXinyun，LIUTiefeng，XIECong，CHENGJingyu，CHENJianping，LUXin，FENGKai，ZHOUYinhua*（WuhanNationalLaboratoryforOptoelectronics，HuazhongUniversityofScienceandTechnology，Wuhan430074，China）AbstractSilvernanowires（AgNWs）areimportantprintabletopelectrodesinflexibleorganicsolarcells（OSCs）.However，whenfabricatingAgNWsfromethanolsolution，itcouldcausedamageonthehole-transportinglayerbelowduetowashingout.Inthiswork，weproposeacross-linkingstrategyonthehole-transportinglayerofpoly（3，4-ethylenedioxythiophene）∶perfluorinatedsulfonicacidionomer（PEDOT∶F）toimproveitsalcoholresistance.Byintroducingacross-linkerofpoly（ethyleneglycol）diglycidylether（PEGDE），PEDOT：Fwassuccessfullycross-linked.Basedonthecross-linkedPEDOT∶Fhole-transportinglayer，small-areaflexibleOSCs（0.041cm2）showedpowerconversionefficiencyof14.86%.Flexibleorganicsolarmodule（21.18cm2）wasthenfabricatedandanefficiencyof12.38%wasachieved.KeywordsHole-transportinglayer；PEDOT∶F；Cross-linking；Silvernanowires；Flexibleorganicsolarcell1IntroductionInrecentyears，organicsolarcells（OSCs）ha...
