山东化工收稿日期:2022-08-07作者简介:曹彪,本科,工程师,现从事硬岩铀矿水冶技术管理工作。某铀矿山离子交换吸附工艺影响因素试验研究曹彪1,段海城1,董宏真1,费亚男2(1.中核韶关锦原铀业有限公司,广东韶关512328;2.中核(广东)科技有限公司,广东韶关512029)摘要:针对某铀矿浸出液离子交换吸附工艺树脂饱和容量低、尾液含量高等问题,通过模拟生产使用的密实移动床,开展室内离子交换吸附条件试验;根据矿石性质和树脂选择性,确定了离子交换吸附工艺的主要影响因素。本次试验主要研究了铀浓度、pH值、Fe3+浓度和Cl-浓度对树脂吸附效果的影响。试验结果表明:浸出液中铀浓度对树脂吸附效果影响较大,pH值、Fe3+浓度和Cl-浓度控制在一定范围内对吸附影响较小。通过本次研究,为铀浸出回收工艺控制提供了依据,有利于降低尾液铀浓度,提高吸附效果,保证各工序有效衔接及稳定运行。关键词:铀;树脂;吸附;影响因素中图分类号:TQ028.3文献标识码:A文章编号:1008-021X(2023)03-0052-03TheExperimentalResearchonInfluencingFactorsofIonExchangeAdsorptionProcessinaUraniumMineCaoBiao1,DuanHaicheng1,DongHongzhen1,FeiYanan2(1.ShaoguanJinyuanUraniumCo.,Ltd.,CNNC,Shaoguan512328,China;2.ChinaNuclear(Guangdong)TechnologyCo.,Ltd.,Shaoguan512029,China)Abstract:Aimingattheproblemsoflowresinsaturationcapacityandhighuraniumconcentrationintherecycledliquidthatintheionexchangeadsorptionprocessofuraniuminleachingsolution,theindoorionexchangeadsorptionconditiontestswerecarriedoutbysimulatingapackedmovingbedusedinproduction.Accordingtothepropertiesofuraniumoreandtheresinselectivety,themaininfluencingfactorsofionexchangeadsorptionprocessweredetermined.Thisexperimentmainlystudiedtheinfluenceofuraniumconcentration,pH,Fe3+concentrationandCl-concentrationontheadsorptioneffectofresin.Theresultsshowthattheconcentrationofuraniuminleachingsolutionhasagreatinfluenceontheadsorptioneffectofresin,whilethepH,theconcentrationofFe3+andCl-controlledwithinacertainrangehaslittleinfluenceontheadsorption.Throughthisexperimentalresearch,thebasisforthecontrolofuraniumleachingandrecoveryprocessisprovided,whichisconducivetoreducingtheconcentrati...